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Q. How do I properly use Unleash Life (UnL)?
A. Use it when you expect the tank to take heavy damage in the next several seconds or when you expect the raid to need healing very shortly. Never use it with Healing Surge (Greater Healing Wave would end up being just as fast with less mana burned), Healing Wave (If the target doesn't need much healing, why are you blowing a 15s cooldown?), or Riptide (same as Healing Wave, except UnL only affects the initial heal.)
The part about riptide is not actually correct, it does increase the effectiveness the hot aswell as the inital heal.
Without UnL the hot tickets for 1590, with UnL it ticks for 1879.
Tested just a few moments ago.